Synthesis, structure, and hydrosilylation catalysis of a chiral A-frame rhodium(I) dimer with cis diphosphite ligands

Authors
Ini, S Oliver, AG Tilley, TD Bergman, RG
Citation
S. Ini et al., Synthesis, structure, and hydrosilylation catalysis of a chiral A-frame rhodium(I) dimer with cis diphosphite ligands, ORGANOMETAL, 20(18), 2001, pp. 3839-3841
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
18
Year of publication
2001
Pages
3839 - 3841
Database
ISI
SICI code
0276-7333(20010903)20:18<3839:SSAHCO>2.0.ZU;2-2
Abstract
This paper reports the synthesis and structure of two new dinuclear chiral rhodium(I) complexes which feature a "cis-A-frame" geometry and their use a s catalysts for the hydrosilylation of aromatic ketones.