A novel full-sandwich lanthanacarborane complex bearing an eta(7)-carboranyl ligand, {{[eta(7)-Me2Si(C13H9)(C2B10H11)](2)Yb-III}(2)Yb-II}{Na-8(THF)(20)}

Authors
Wang, SW Li, HW Xie, ZW
Citation
Sw. Wang et al., A novel full-sandwich lanthanacarborane complex bearing an eta(7)-carboranyl ligand, {{[eta(7)-Me2Si(C13H9)(C2B10H11)](2)Yb-III}(2)Yb-II}{Na-8(THF)(20)}, ORGANOMETAL, 20(18), 2001, pp. 3842-3844
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
18
Year of publication
2001
Pages
3842 - 3844
Database
ISI
SICI code
0276-7333(20010903)20:18<3842:ANFLCB>2.0.ZU;2-O
Abstract
The first full-sandwich lanthanacarborane containing an eta (7)-carboranyl ligand was prepared and structurally characterized, which indicates that th e arachno-carboranyl ligand can effectively stabilize the high oxidation st ate of the metal.