A. De Graaf et al., Investigation of processes in low-pressure expanding thermal plasmas used for carbon nitride deposition: II. Ar/N-2 plasma with graphite nozzle, PLASMA SOUR, 10(3), 2001, pp. 524-529
The chemistry of an argon/nitrogen thermal plasma expanding through a graph
ite nozzle is investigated in order to unravel the role of plasma species i
n the deposition (1-3 nm s(-1) rate) of non-hydrogenated amorphous carbon n
itride (a-C:N) films. The spectral emission of plasma species is studied an
d is used in combination with mass spectrometry and nozzle temperature meas
urements to distinguish possible mechanisms of species production and excit
ation.