S. Sathyamurthy et K. Salama, Chemical cleaning treatment of textured nickel for the deposition of epitaxial thin films, SUPERCOND S, 14(8), 2001, pp. 643-645
Coated conductors employing rolling-assisted-biaxially-textured-substrates
offer a viable alternative to the BSCCO power-in-tube tapes. These conducto
rs are based on the deposition of biaxially oriented buffer layers and YBCO
films on textured nickel alloy substrates. Researchers are becoming increa
singly aware that the cleanliness of the nickel surface plays a crucial rol
e in making it conducive to epitaxial film deposition. Several cleaning tec
hniques are currently being explored. In this work we report the results ob
tained from a simple chemical cleaning procedure based on an aqueous soluti
on of formic acid and hydrogen peroxide. X-ray photoelectron spectroscopy s
tudies were performed to understand the effect of the cleaning treatment on
the nickel surface. It was found that the cleaning treatment significantly
enhances the ability of the nickel to act as a crystallographic template f
or the deposition of strontium titanate using a metallorganic decomposition
process. These results give promise for the development of scalable cleani
ng procedures for coated conductor applications.