Selective halogenation of aromatics by dimethyldioxirane and halogen ions

Authors
Bovicelli, P Mincione, E Antonioletti, R Bernini, R Colombari, M
Citation
P. Bovicelli et al., Selective halogenation of aromatics by dimethyldioxirane and halogen ions, SYN COMMUN, 31(19), 2001, pp. 2955-2963
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
19
Year of publication
2001
Pages
2955 - 2963
Database
ISI
SICI code
0039-7911(2001)31:19<2955:SHOABD>2.0.ZU;2-Y
Abstract
The oxidation of halogen anions by dimethyldioxirane (DMD) produced reactiv e species which led, in acidic media, to the halogenation of activated arom atic rings. The reaction can be efficiently controlled to obtain selective and mixed halogenated species.