Crystal structure, electrical transport, electronic band structure and quantum oscillations studies of the organic conducting salt theta-(BETS)(4)HgBr4(C6H5Cl)
Rb. Lyubovskii et al., Crystal structure, electrical transport, electronic band structure and quantum oscillations studies of the organic conducting salt theta-(BETS)(4)HgBr4(C6H5Cl), SYNTH METAL, 123(1), 2001, pp. 149-155
The theta-(BETS)(4)HgBr4(C6H5Cl) radical cation salt was prepared by electr
ochemical crystallization. Its crystal structure was determined by single c
rystal X-ray diffraction. The electronic structure was studied by means of
the extended Huckel tight-binding band approximation. Electrical resistance
of theta-(BETS)(4)HgBr4(C6H5Cl) as a function of temperature shows a metal
lic behavior down to 14 K with a metal-semiconductor-metal transition withi
n 240-246 K range. Shubnikov-de Haas oscillations showed a low-frequency sp
ectrum with two frequencies F-1 = 40 T and F-2 = 210 T, which correspond to
the proposed Fermi surface. The third frequency which has to be observed a
ccording to the calculations was not revealed in the experimental condition
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