Novel packing type of ET radical cation layers in a new organic conductor (ET)(5)[Dy(NCS)(6)NO3]center dot C2H5OH with a metal-complex lanthanide anion

Authors
Kushch, ND Kazheva, ON Gritsenko, VV Buravov, LI Van, KV Dyachenko, OA
Citation
Nd. Kushch et al., Novel packing type of ET radical cation layers in a new organic conductor (ET)(5)[Dy(NCS)(6)NO3]center dot C2H5OH with a metal-complex lanthanide anion, SYNTH METAL, 123(1), 2001, pp. 171-177
Citations number
20
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
123
Issue
1
Year of publication
2001
Pages
171 - 177
Database
ISI
SICI code
0379-6779(20010822)123:1<171:NPTOER>2.0.ZU;2-T
Abstract
A new radical cation (ET)(5)[Dy(NCS)(6)NO3].C2H5OH salt was prepared by ele ctrochemical oxidation of ET in a chlorobenzene-ethanol solution. Its cryst al structure and conducting properties were examined. The salt has a layere d crystal structure with a basically new packing type of the radical cation layer, which was called an co-type. Resistance studies reveal a semiconduc ting nature of this salt. (C). 2001 Elsevier Science B.V. All rights reserv ed.