Synthesis of disaccharides containing alpha-linked GlcNAc or beta-linked ManNAc units

Authors
Drew, MGB Ennis, SC Gridley, JJ Osborn, HMI Spackman, DG
Citation
Mgb. Drew et al., Synthesis of disaccharides containing alpha-linked GlcNAc or beta-linked ManNAc units, TETRAHEDRON, 57(37), 2001, pp. 7919-7937
Citations number
44
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
57
Issue
37
Year of publication
2001
Pages
7919 - 7937
Database
ISI
SICI code
0040-4020(20010910)57:37<7919:SODCAG>2.0.ZU;2-9
Abstract
The synthesis of disaccharides containing alpha -linked GlcNAc or beta -lin ked ManNAc units from shelf-stable, and yet highly reactive, 2-oximinoglyco syl donors is described. Access to a preponderance of the disaccharides con taining either the alpha -linked GlcNAc or beta -Linked ManNAc unit can be obtained by careful choice of solvent and glycosidation conditions. (C) 200 1 Elsevier Science Ltd. All rights reserved.