We describe a vertically scanning infrared radiometer for measuring the air
-sea temperature difference without disturbing the water skin layer. The ra
diometer operates with a single wavelength channel that is 1.1 mum wide, ce
ntered on 14.2 mum, on the short-wavelength edge of a CO2 atmospheric absor
ption band. The resulting high atmospheric absorption enables calibration o
f the horizontal-viewing signal with an in situ air-temperature sensor. The
signal at all other scan angles is measured relative to that at the horizo
ntal, providing a differential air-sea temperature measurement that is near
ly independent of calibration offsets that can be a problem with independen
t air- and water-temperature sensors. We show data measured on a ship in th
e Tropical Western Pacific Ocean during July 1999, which exhibit important
discrepancies from in situ data using bulk air- and water-temperature senso
rs. These discrepancies illustrate important differences between bulk versu
s skin water temperature. (C) 2001 Optical Society of America.