We present new radial velocity data for eleven classical Cepheids situated
in the outer parts of the Galactic disc. The resultant velocity curves for
these metal-deficient Cepheids are decomposed in Fourier parameters, and co
mpared to solar-metallicity Cepheid data, in order to study the effect of m
etallicity on the pulsation properties. Up to P similar or equal to 8 days,
the phi (21) phase shift is found to follow very closely the corresponding
sequence for solar-metallicity Cepheids, indicating the absence of metalli
city effects on phi (21) for low periods. However, metal-deficient Cepheids
show a slightly larger A(1) amplitude and R-21 amplitude ratio for P <5 da
ys. At P >12 days, there is some evidence that the phi (21) phase shift is
significantly larger for metal-deficient Cepheids than at solar metallicity
. A posteriori, this effect is also detected in photometric data for outer
disc and LMC Cepheids in the 12-20 day period range. In good qualitative ag
reement with the predictions of theoretical pulsation models, we therefore
see some indication of a metallicity dependence of the P-2/P-0 resonance pr
operties. The largest effects on velocity curve shape are expected in the c
rucial 8-12 day period range - around the P-2/P-0 resonance for fundamental
-mode Cepheids - that is not covered by our data. Possible targets for futu
re measurements are suggested to fill this gap, and to improve the quantita
tive determination of metallicity effects on the structural properties of C
epheid velocity curves.