In aggressive environments, concrete itself may not be enough to protect th
e reinforcement against carbon dioxide penetration. This gas reacts with th
e portlandite of the concrete to form calcium carbonate. This process leads
to a pH reduction and, therefore, promotes the depassivation of the steel
reinforcement in reinforced concretes. Therefore, a supplementary protectio
n method such as coating with a mortar. as carbonation barrier can be used
to provide adequate durability. Experimental data are presented to illustra
te the effect of three different testing levels of CO2 on an industrial mor
tar applied to a concrete base in order to evaluate its performance as an a
nti-carbonation barrier. The results from the coated concrete are compared
with the carbonation resistance of the uncoated plain concrete. The carbona
tion depth was determined using a phenolphthalein pH-indicator. A clear red
uction in carbonation was observed when the mortar was applied. The validit
y of the accelerated testing method, which consists of placing the mortar i
n a high carbon dioxide concentration chamber for a controlled time, and ca
rbonation coefficients to assess coating effectiveness are discussed. The u
se of 100% carbon dioxide is highly questionable for accelerated carbonatio
n testing. (C) 2001 Elsevier Science Ltd. All rights reserved.