The hardening mechanism of a paste composed of a low calcium fly ash and al
kali was investigated. It was found that a fraction of fly ash reacted with
water-glass and formed amorphous or low-ordered crystalline compounds of t
he type of Na2O-Al2O3-SiO2, after the paste was cured at 60 degreesC for 24
h. For the water-glass with a modulus of 1.64, the strength of the paste i
s mainly attributed to the gel-like reaction products that bind the particl
es of fly ash together. When the modulus is decreased to 1.0, crystalline s
odium silicate is formed in the matrix, which helps to achieve high strengt
hs. (C) 2001 Elsevier Science Ltd. All rights reserved.