Full temporal resolution of the two-step photoinduced energy-electron transfer in a fullerene-oligothiophene-fullerene triad using sub-10 fs pump-probe spectroscopy

The intramolecular photoinduced energy and electron transfer in a fullerene -oligothiophene-fullerene triad with nine thiophene units (C-60-9T-C-60) ha s been investigated with sub-10 fs pump-probe spectroscopy in solvents of d ifferent polarity. Photoexcitation of the oligothiophene moiety results in an ultrafast singlet-energy transfer reaction to create the fullerene singl et-excited state with a time constant of 95 fs, irrespective of the polarit y of the medium. In a polar solvent, the ultrafast singlet-energy transfer is followed by intramolecular electron transfer from the oligothiophene to the fullerene with a time constant of 10 ps, resulting in a charge-separate d state (CSS) with a lifetime of 80 ps. (C) 2001 Elsevier Science B.V. All rights reserved.