Infrared reflectance. and transmission measurements as well as Raman scatte
ring have been used to study the RE1+xBa2-xCu3O6 (RE = Nd, Sm) and YBa2Cu3O
6 absorption bands in the 1100-1500 cm(-1) infrared range as a function of
temperature and beam polarization. In addition to two-phonon absorption bet
ween 1100 and 1170 cm(-1), we observe excitations around 1400 cm(-1). occur
ring in oxygen rich enclosures within the samples, and assign them to an ex
citation involving two-phonons plus the 270 cm(-1) local mode related to Cu
-O broken chains. Thus, the previously reported possible magnetic origin of
the 1436 cm(-1) sharp absorption band in YBa2Cu3O6 is contested.