Ring-driven shear thickening in wormlike micelles?

Citation
Me. Cates et Sj. Candau, Ring-driven shear thickening in wormlike micelles?, EUROPH LETT, 55(6), 2001, pp. 887-893
Citations number
32
Categorie Soggetti
Physics
Journal title
EUROPHYSICS LETTERS
ISSN journal
02955075 → ACNP
Volume
55
Issue
6
Year of publication
2001
Pages
887 - 893
Database
ISI
SICI code
0295-5075(200109)55:6<887:RSTIWM>2.0.ZU;2-C
Abstract
The shear-thickening behaviour of wormlike micelles, at concentrations just below overlap, remains unexplained. In some cases, it has recently been co nfirmed that very slow relaxations must be present even in the quiescent st ate for example, the shear-thickening properties can depend on earlier ther mal cycling. We present a speculative scenario based on the presence, just below the ( apparent) overlap threshold, of large rings whose linking and d elinking kinetics control the shear-thickening process. Equilibration betwe en rings and open chains in turn controls the slow relaxations.