Multidimensional quantum propagation with the help of coupled coherent states

Citation
Dv. Shalashilin et Ms. Child, Multidimensional quantum propagation with the help of coupled coherent states, J CHEM PHYS, 115(12), 2001, pp. 5367-5375
Citations number
37
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
115
Issue
12
Year of publication
2001
Pages
5367 - 5375
Database
ISI
SICI code
0021-9606(20010922)115:12<5367:MQPWTH>2.0.ZU;2-#
Abstract
A previous initial value coupled coherent state (CCS) representation is app lied to Gaussian wave packet propagation on multidimensional Henon Heiles p otentials. Solutions of the time-dependent integro-differential Schrodinger equation are obtained in a basis of trajectory guided Frozen Gaussian Cohe rent States, with Monte Carlo sampling to ensure a unique capability for pr opagating multidimensional wave functions. Results, which are obtained for up to 14 D, are compared with those derived by the Herrnan-Kluk semiclassic al initial value representation (IVR) wave packet method. (C) 2001 American Institute of Physics.