Scope and limitation of intramolecular Pauson-Khand reaction of fluorine-containing enynes

Authors
Ishizaki, M Suzuki, D Hoshino, O
Citation
M. Ishizaki et al., Scope and limitation of intramolecular Pauson-Khand reaction of fluorine-containing enynes, J FLUORINE, 111(1), 2001, pp. 81-90
Citations number
36
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
111
Issue
1
Year of publication
2001
Pages
81 - 90
Database
ISI
SICI code
0022-1139(20010928)111:1<81:SALOIP>2.0.ZU;2-R
Abstract
Intramolecular Pauson-Khand reaction of various fluorine-containing enynes was investigated under various conditions. The reaction of the substrates. which have fluorine atom(s) or fluorine-containing group(s) attached to alk enyl moiety, gave the corresponding cyclopentenones in low to moderate yiel d, while that of the substrates bearing fluorine-containing groups attached to alkynyl moiety afforded the corresponding cyclopentenones in low to hig h yield. (C) 2001 Elsevier Science B.V. All rights reserved.