The compositional variation of the fatty acid, triacylglycerol, tocopherol,
tocotrienol and sterene composition of genuine cocoa butter (CB) due to di
fferent geographical growing regions and breeding lines as well as other ve
getable fats used in confectionery manufacturing (cocoa butter equivalents,
CBE) have been investigated. Genuine CB showed quite narrow ranges of comp
ositional variation compared to CBEs. CBEs are prepared by blending differe
nt tropical fats to suit various technological requirements of confectioner
y manufacturers. Consequently, no consistent compositional patterns were ob
served within the latter group. The fatty acid and the triacylglycerol data
presented could be utilized for the detection as well as the quantificatio
n of CBEs in plain chocolate, by using appropriate calibration models. Howe
ver, the minor constituents (tocopherols, -trienols, and sterene data) are
of limited use for quantitative purposes, but may be additional indicators
for the presence of other vegetable fats in chocolate. (C) 2001 Academic Pr
ess.