The standardisation of near infrared instruments using master selection and Wiener filter methods

Citation
Jj. Siska et Cr. Hurburgh, The standardisation of near infrared instruments using master selection and Wiener filter methods, J NEAR IN S, 9(2), 2001, pp. 107-116
Citations number
16
Categorie Soggetti
Agricultural Chemistry","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF NEAR INFRARED SPECTROSCOPY
ISSN journal
09670335 → ACNP
Volume
9
Issue
2
Year of publication
2001
Pages
107 - 116
Database
ISI
SICI code
0967-0335(2001)9:2<107:TSONII>2.0.ZU;2-Z
Abstract
In this report, two aspects of near infrared standardisation (calibration t ransfer) were studied: the selection of the master instrument and the stand ardisation algorithm. Their impact on the accuracy of barley protein measur ements was evaluated using 285 fixed-filter Foss Grainspec instruments. Opt ical linear regression, Wiener filter and no standardisation were compared. The statistically-based master selection procedure had a significant impac t on the spectral and calibration transfer when all standardisation techniq ues were applied. Spectral centralisation improved the accuracy of predicti on, particularly when a poorer master was used.