Determination of sorption isotherms for Eu, Th, U and Am on the gel layer of corroded HLW glass

The retention of Eu(III). Th(IV), U(VI) and Am(III) in the alteration layer (gel layer) of precorroded simulated HLW glass is investigated by sorption experiments in water, NaCl and MgCl2 brine as a function of the pH. In wat er, the sorption behaviour of the four elements shows a strong dependence o n the pH and the sorption coefficients (R-5) determined reflect the differe nt charges of the three ions and the corresponding sorption properties. The R-5 values of Th are the highest values, followed by the R-5 values of Eu and Am, which are lower by about a factor of 10 at the respective pH. and f inally by the R-5 values of U(VI) which are the lowest. The sorption behavi our of the four elements can be described by a Langmuir isotherm for pH val ues <5. As shown by modelling calculations. the strong increase of the R-5 values of Eu and Am, as well as of Th. with increasing pH can be described by the formation of a bidentate surface complex. Above pH 4-6, colloidal pa rticles could be detected. From the concentrations of Nd in the solutions l eached from the glass. 'desorption' coefficients (R-d) Of Nd can be calcula ted. The R-d values of Nd correspond quite well with the R-5, data of the c hemically homologue Eu and Am. In NaCl brine the sorption behaviour of Th a nd U is rather similar to that in water, whereas in MgCl2 brine the sorptio n of Eu, Am, and U in the gel layer is much lower than in water or NaCl bri ne. The results of the sorption tests can explain the very low release and solution concentrations of REE and actinides found in corrosion experiments with the radioactive CEA glass R7T7 in NaCl-rich solution under neutral to alkaline conditions. (C) 2001 Elsevier Science B.V. All rights reserved.