K. Takenaka et Y. Kawamoto, Fabrication of hybrid material by coating of bioactive glass-ceramic on alumina substrate through porcelain enamel process, J CERAM S J, 109(9), 2001, pp. 733-737
In artificial bones, a steady bioactivity over long-term service, no dissol
ution of harmful ions and a sufficient mechanical strength are required, th
ough the relative importance of the above factors depends upon the implanta
tion place. In general, bioactive materials have no sufficient mechanical s
trength and, on the other hand, materials with high mechanical strength are
not bioactive. In the present study, a porcelain enamel technique was appl
ied to produce a hybrid material whose both bioactivity and high mechanical
strength, which merely consists of inorganic materials. High-strength alum
ina and bioactive glass-ceramics were used as substrate and coating materia
l, respectively, and an adhesion-glass was employed to achieve a tight bond
between alumina and the bioactive glass-ceramic. Appropriate heat-treatmen
ts of the alumina, adhesion-glass and bioactive glass-ceramic composite res
ulted in the successful production of a hybrid material that has about 2.5
times stronger in bending-strength than that of an apatite precipitation-ty
pe glass-ceramic. This technique gives a useful process on production of ce
ramic-ceramic hybrid materials with high mechanical strength and bioactivit
y for bone substitution.