Cl. Xu et al., A mechanism of diamond growth with carbon nanotube nucleation agent by hot-filament chemical vapor deposition, MATER TRANS, 42(8), 2001, pp. 1753-1757
Behaviors of carbon nanotubes (CNTs) in H-2 atmosphere or CH4 + H-2 mixture
s, transforming mechanism of CNTs to diamond embryo were investigated. Expe
rimental results show that CNTs could be etched by H-2 and transformed to c
arbon nanoparticles under conditions of hot-filament chemical vapor deposit
ion. The mechanism can be concluded that CNTs were broken down by H-2, tran
sformed to carbon nanoparticles or shorter CNTs; on surface of carbon nanop
articles or end caps of CNTs diamond crystals were nucleated and grown up.