A mechanism of diamond growth with carbon nanotube nucleation agent by hot-filament chemical vapor deposition

Citation
Cl. Xu et al., A mechanism of diamond growth with carbon nanotube nucleation agent by hot-filament chemical vapor deposition, MATER TRANS, 42(8), 2001, pp. 1753-1757
Citations number
20
Categorie Soggetti
Material Science & Engineering
Journal title
MATERIALS TRANSACTIONS
ISSN journal
13459678 → ACNP
Volume
42
Issue
8
Year of publication
2001
Pages
1753 - 1757
Database
ISI
SICI code
1345-9678(200108)42:8<1753:AMODGW>2.0.ZU;2-O
Abstract
Behaviors of carbon nanotubes (CNTs) in H-2 atmosphere or CH4 + H-2 mixture s, transforming mechanism of CNTs to diamond embryo were investigated. Expe rimental results show that CNTs could be etched by H-2 and transformed to c arbon nanoparticles under conditions of hot-filament chemical vapor deposit ion. The mechanism can be concluded that CNTs were broken down by H-2, tran sformed to carbon nanoparticles or shorter CNTs; on surface of carbon nanop articles or end caps of CNTs diamond crystals were nucleated and grown up.