Hexagonal arrays of silicon nanopillars have been fabricated in a silicon-o
n-insulator wafer using a patterned metal layer as a mask for reactive ion
etching. The metal mask is created by deposition through a self-assembled m
onolayer of polymer particles. In the case of a silver mask, we find that t
he quality of the pillars depends on the wetting of the exposed silicon reg
ions in the interstitial sites between the polymer balls, which in turn dep
ends on the deposition parameters, such as pressure and deposition rate. Go
ld is found to wet the silicon, producing smooth masks which lead to pyrami
dal silicon structures after etching. (C) 2001 Elsevier Science B.V. All ri
ghts reserved.