Citation
Bm. Cheng et al., Photodissociation thresholds of OH produced from CH3OH in solid neon and argon, NUCL INST A, 467, 2001, pp. 1461-1464
Citations number
16
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences","Instrumentation & Measurement
Journal title
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT
ISSN journal
01689002
→ ACNP
Volume
467
Year of publication
2001
Part
2
Pages
1461 - 1464
Database
ISI
SICI code
0168-9002(20010721)467:<1461:PTOOPF>2.0.ZU;2-2
Abstract
Photodissociation thresholds of OH from CH3OH in solid Ne and Ar were deter
mined via photolysis of CH3OH/Ne and CH3OH/Ar (1/200) samples in situ at 4
K. The samples were irradiated with VUV synchrotron radiation after dispers
ion by a Seya-Namioka monochromator. The OH photo-product was detected by m
eans of laser-induced fluorescence technique. The increase of fluorescent i
ntensity of OH was monitored and recorded after the matrix sample was irrad
iated at different wavelengths for 3-5 min. Photodissociation threshold ene
rgies of 7.13 +/- 0.02 eV (174.0 +/- 0.5 nm) and 7.08 +/- 0.04 eV (175.0 +/
- 1.0 nm) were measured for OH production of CH3OH in solid Ne and Ar, resp
ectively. (C) 2001 Elsevier Science B.V. All rights reserved.