A concise synthesis of turneforcidine via a metalloiminium ion cyclizationterminated by the 2-(methylthio)-3-(trimethylsilyl)-1-propenyl moiety

Authors
An, DK Duncan, D Livinghouse, T Reid, P
Citation
Dk. An et al., A concise synthesis of turneforcidine via a metalloiminium ion cyclizationterminated by the 2-(methylthio)-3-(trimethylsilyl)-1-propenyl moiety, ORG LETT, 3(19), 2001, pp. 2961-2963
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
19
Year of publication
2001
Pages
2961 - 2963
Database
ISI
SICI code
1523-7060(20010920)3:19<2961:ACSOTV>2.0.ZU;2-D
Abstract
[GRAPHICS] A concise synthetic route to racemic turneforcidine (1) is described that r elies on the stereocontrolled cyclization of the 2-(methylthio)-3-(trimethy lsilyi)-1-propenyl bearing imine 5 in the presence of TiCl4.