Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr '(4)] (HL=6-Me-2,2 '-bipyridine, Ar '=3,5-(CF3)(2)C6H3), an intermediate relevant to ethene/CO copolymerization

Authors
Stoccoro, S Minghetti, G Cinellu, MA Zucca, A Manassero, M
Citation
S. Stoccoro et al., Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr '(4)] (HL=6-Me-2,2 '-bipyridine, Ar '=3,5-(CF3)(2)C6H3), an intermediate relevant to ethene/CO copolymerization, ORGANOMETAL, 20(19), 2001, pp. 4111-4113
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
19
Year of publication
2001
Pages
4111 - 4113
Database
ISI
SICI code
0276-7333(20010917)20:19<4111:SAMSO[>2.0.ZU;2-#
Abstract
In the ethene/CO copolymerization catalyzed by palladium derivatives, speci es arising from ethene insertion into the palladium-acyl bond have been sho wn to play a key role. We report here the synthesis, spectroscopic characte rization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr ' ( 4)] (HL = 6-Me-2,2 ' -bipyridine, Ar ' = 3,5-(CF3)(2)C6H3), 4, the first on e having an ancillary N,N ligand to be characterized in the solid state.