First heterobimetallic seven-membered macrocycle complex with a Fe(0) -> Cu(I) donor-acceptor bond

Authors
Cui, DJ Li, QS Xu, FB Leng, XB Zhang, ZZ
Citation
Dj. Cui et al., First heterobimetallic seven-membered macrocycle complex with a Fe(0) -> Cu(I) donor-acceptor bond, ORGANOMETAL, 20(19), 2001, pp. 4126-4128
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
19
Year of publication
2001
Pages
4126 - 4128
Database
ISI
SICI code
0276-7333(20010917)20:19<4126:FHSMCW>2.0.ZU;2-M
Abstract
A new ligand, 2-(N-diphenylphosphinomethyl-N-cyclohexyl)aminopyridine (NNP) , was prepared by the Mannich reaction of HPPh2 with 2-(N-cyclohexyl)aminop yridine and paraformaldehyde. The ligand NNP reacted with Fe(CO)(5) to give the monometallic complex trans-Fe(CO)(3)(NNP)(2) (2). The reaction of comp lex 2 with [Cu(CH3CN)(4)](+)[ClO4](-) gave a novel complex 3, [(OC)(3)Fe(mu -NNP)(2)CU]+ClO4-, which has two seven-membered macrocycles and an Fe(O) - -> Cu(I) donor-acceptor bond. The molecular structure of complex 3 was dete rmined by X-ray single-crystal analysis.