Interfacial interactions between protein and lipid in edible emulsion
films are thought to reduce water vapor permeability (WVP). Films were
prepared from whey protein isolate, glycerol and emulsified lipid (tr
iolein or tripalmitin/butterfat blend). The interfacial composition wa
s varied using sodium dodecyl sulfate. Particle size and WVP were dete
rmined by laser light scattering and gravimetric methods respectively.
Shear treatment significantly reduced the WVP of the protein phase. I
nterfacial interactions were small in triolein films and were not dete
cted in tripalmitin/butterfat films. WVP did not depend strongly on th
e physical state of the dispersed phase. The distribution of the lipid
droplets within the film is the primary determinant of WVP in the sys
tems studied.