THE FIRST MOLECULE INCORPORATING [ETA(5)-NC4H4](-) AND AN ORGANIC C-NC4H4 GROUP - SYNTHESIS OF [CO(7-C4H4N(CH2)(3)-8-R-7,8-C2B9H9)(ETA(5)-NC4H4)] (R=CH3, C6H5)
S. Gomez et al., THE FIRST MOLECULE INCORPORATING [ETA(5)-NC4H4](-) AND AN ORGANIC C-NC4H4 GROUP - SYNTHESIS OF [CO(7-C4H4N(CH2)(3)-8-R-7,8-C2B9H9)(ETA(5)-NC4H4)] (R=CH3, C6H5), Inorganic chemistry, 36(16), 1997, pp. 3565
The synthesis of Co(7-C4H4N(CH2)(3)-8-R-7,8-C2B9H9)-(eta(5)-NC4H4)] (R
= CH3, C6H5), the first molecule reported incorporating [eta-NC4H4](-
) and an organic C-NC4H4 group, is described. The molecular structure
of the compound for R = CH3 is indicated in the diagram.