Heavy metal separation capacity of a porous methacrylamidophenylalanine containing membrane based on a polyhydroxyethyl methacrylate matrix

The abilities of various sorbent materials for heavy metal removal have bee n reported in the literature. We have developed a novel approach to obtain high metal-sorption capacity utilizing a membrane containing 2-methacrylami dophenylalanine. Metal-complexing ligand 2-methacrylamidophenylalanine (MAP A) was synthesized through the use methacrylo chloride and phenylalanine. T hen, poly(2-hydroxyethyhmethacrylate-co-2-methacrylamidophenylalanine) (p(H EMA-co-MAPA)) membranes were prepared by UV-initiated photopolymerization o f HEMA and MAPA in the presence of the initiator azobisisobutyronitrile. MA PA monomer was characterized by nuclear magnetic resonance spectroscopy. p( HEMA-co-MAPA) membranes were characterized by swelling studies, scanning el ectron microscopy, Fourier transform infrared spectroscopy, and elemental a nalysis. These membranes have large pores; the micropore dimensions are app roximately 5-10 mum. p(HEMA-co-MA-PA) affinity membranes with a swelling ra tio of 133.2% and containing 18.9 mmol MAPA/m(2) were used in the removal o f the heavy-metal ions of copper, nickel, and mercury from aqueous media co ntaining different amounts of these ions (5-600 mg/L) and at different pH v alues (2.0-7.0). The maximum adsorption capacities of heavy metal ions onto the MAPA-containing membranes under noncompetitive conditions were 23.8 = mmol/m(2) for Cu(II), 29.1 mmol/m(2) for Ni(II), and 50.3 mmol/m(2) for Hg( II). The affinity order was Hg(II) > Ni(II) > Cu(II). The adsorption of hea vy metal ions increased with increasing pH and reached a plateau value at a pproximately pH 5.0. Adsorption of heavy metal ions from artificial wastewa ter was also studied. The adsorption capacities were 11.9 mmol/m(2) for Cu( II), 7.33 mmol/m(2) for Ni(II), and 9.79 mmol/m(2) for Hg(II). Desorption o f heavy metal ions was performed using 0.1 M HNO3. The p(HEMA-co-MAPA) memb ranes are suitable for more than five cycles without noticeable loss of cap acity.