The hydrolysis and polymerization of polyferric sulfate (PFS) were characte
rized. Jar test experiments were conducted to evaluate the coagulations of
PFS, ferric chloride, and polyaluminum chloride. A pilot water-treatment pl
ant consisting of coagulation, sedimentation, and filtration processes at a
capacity of 30 1/h was simulated to analyze the effect of coagulant types
on their performances. Results show that PFS leaves less iron residual and
yields more efficient removals of turbidity and color than equivalent doses
of conventional coagulants.