Carbon nitride thin films were prepared by the electron-gun evaporation of
high purity carbon under concurrent bombardment with nitrogen ion-beam. The
base vacuum reached 10(-4) Pa and the operating vacuum pressure was approx
imately 10(-2) Pa. The purity of the nitrogen gas was 99.99% and the ion-be
am energy was 500-1000 eV. It was found that the deposition rate decreased
with increase of the ion beam energy. The films deposited at different cond
itions were studied by X-ray photoelectron spectroscopy (XPS) and energy di
spersive X-rays (EDX). The XPS data showed that C-N sp(2) and C-N sp(3) bon
ds existed in the films. The result with the maximum NIC atomic ratio of 0.
43 was obtained from EDX measurements. The films tested by nano indentation
had the maximum knoop hardness value of 23 GPa. The experiments of atomic
oxygen action and cold welding in an ultra high vacuum environment proved t
hat the films had good anti-atomic oxygen and anti-cold welding properties,
and would have broad application prospects in space environments. (C) 2001
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