Elastic electron backscattering probability for Au overlayers deposited on
Ni were determined experimentally in the energy range 200-1000 eV. These me
asurements were accompanied by characterization of the overlayer structure
and the mean overlayer thickness. The elastic backscattering probabilities
also were derived from extensive Monte Carlo simulations of the electron tr
ansport in overlayer/substrate systems. Two overlayer structures were consi
dered in these calculations: a uniform Au layer, and isolated Au islands lo
cated on the uncovered substrate. Analysis of the shape of Au 4d spectra wi
th QUASES-Tougaard software indicated that the latter structure is more pro
bable. It has been found that the experimental elastic backscattering proba
bilities compare better with the theoretical probabilities calculated for t
he island structure. The possibility of characterization of the overlayer t
hickness and structure from the elastic backscattering probabilities has be
en discussed. Copyright (C) 2001 John Wiley & Sons, Ltd.