Electrochemical behaviour of 3,8-difluorobenzo[c]cinnoline at mercury electrode

Citation
Z. Durmus et al., Electrochemical behaviour of 3,8-difluorobenzo[c]cinnoline at mercury electrode, TALANTA, 55(2), 2001, pp. 357-362
Citations number
17
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
TALANTA
ISSN journal
00399140 → ACNP
Volume
55
Issue
2
Year of publication
2001
Pages
357 - 362
Database
ISI
SICI code
0039-9140(20010830)55:2<357:EBO3AM>2.0.ZU;2-J
Abstract
Voltametric and coulometric methods have been used to study the electroanal ytical behaviour of 3,8-difluorobenzo[c]cinnoline. The number of electrons transferred, the wave characteristics, diffusion coefficient and reversibil ity of the reactions have been investigated in ethyl alcohol-BR. Adsorption of the molecule on the surface of the mercury drop electrode was analyzed and this phenomena was exploited to calculate the diffusion coefficient of 3,8-difluorobenzo[c]cinnoline. A mechanism for the electrode reaction was p roposed. (C) 2001 Elsevier Science B.V. All rights reserved.