X-ray diffraction shows that the title cadmium(II) complex, [Cd-2(C14H20O2)
(2)(C5H5N)(6)](.)2C(5)H(5)N, has a dimeric structure in which two (py)(3) C
d(3,5-di-tert-butylcatecholate) units (py is pyridine) are connected by two
bridging O atoms, the coordination of the Cd atoms being distorted octahed
ral. There are two symmetrically independent dimers in the crystal structur
e; one is in a general position and the other lies about an inversion centr
e. In both cases, the bridging Cd-O distances between the Cd-catecholate un
its [2.224 (2)-2.237 (2) Angstrom] are shorter than the bridging Cd-O dista
nces within the catecholate cycle [2.273 (2)-2.281 (2) Angstrom]. The Cd-N-
py distances are 2.354 (2)-2.471 (2) Angstrom. Besides the main molecules,
the crystal also contains pyridine solvate molecules.