Bis(mu-3,5-di-tert-butylcatecholato-O-1 : O-1,O-2)bis[tris(pyridine-N)-cadmium(II)] dipyridine solvate

Citation
Gk. Fukin et al., Bis(mu-3,5-di-tert-butylcatecholato-O-1 : O-1,O-2)bis[tris(pyridine-N)-cadmium(II)] dipyridine solvate, ACT CRYST C, 57, 2001, pp. 1020-1021
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
1020 - 1021
Database
ISI
SICI code
0108-2701(200109)57:<1020:B:O>2.0.ZU;2-R
Abstract
X-ray diffraction shows that the title cadmium(II) complex, [Cd-2(C14H20O2) (2)(C5H5N)(6)](.)2C(5)H(5)N, has a dimeric structure in which two (py)(3) C d(3,5-di-tert-butylcatecholate) units (py is pyridine) are connected by two bridging O atoms, the coordination of the Cd atoms being distorted octahed ral. There are two symmetrically independent dimers in the crystal structur e; one is in a general position and the other lies about an inversion centr e. In both cases, the bridging Cd-O distances between the Cd-catecholate un its [2.224 (2)-2.237 (2) Angstrom] are shorter than the bridging Cd-O dista nces within the catecholate cycle [2.273 (2)-2.281 (2) Angstrom]. The Cd-N- py distances are 2.354 (2)-2.471 (2) Angstrom. Besides the main molecules, the crystal also contains pyridine solvate molecules.