Chloro(3,6,13,16-tetraethyl-2,7,12,-17-tetramethylporphycenato-kappa N-4)-iron(III) chloroform solvate

Authors
Ohgo, Y Neya, S Ikeue, T Funasaki, N Nakamura, M
Citation
Y. Ohgo et al., Chloro(3,6,13,16-tetraethyl-2,7,12,-17-tetramethylporphycenato-kappa N-4)-iron(III) chloroform solvate, ACT CRYST C, 57, 2001, pp. 1046-1047
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
1046 - 1047
Database
ISI
SICI code
0108-2701(200109)57:<1046:CN>2.0.ZU;2-E
Abstract
The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20 -tetraethyl-4,9,14,19-tetramethylpentacyclo- [16.2.1.1(2,5).1(8,11).1(12,15 )]tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform s olvate, [Fe(C33H37N4)Cl]. CHCl3, reveals a twisted macrocyclic framework wi th a slightly distorted rectangular pyramidal core, where the deviation of the central Fe III atom from the least-squares plane of the C20N4 core is 0 .594 (1) Angstrom. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Angstrom; Fe-Cl 2.232 (1) Angstrom .