A layered tin(II) phosphonate, [Sn(C6H5O3P)](n)

Authors
Lansky, DE Zavalij, PY Oliver, SRJ
Citation
De. Lansky et al., A layered tin(II) phosphonate, [Sn(C6H5O3P)](n), ACT CRYST C, 57, 2001, pp. 1051-1052
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
1051 - 1052
Database
ISI
SICI code
0108-2701(200109)57:<1051:ALTP[>2.0.ZU;2-#
Abstract
Poly[tin(II)-mu -phenylphosphonato], [Sn(C6H5O3P)](n), was synthesized solv othermally at 423 K and crystallized in the monoclinic system, space group Cc. The inorganic layers consist of alternating pyramidal Sn and tetrahedra l P centers, joined by doubly bridging O atoms. The corner-sharing SnO3 and PO3C6H5 polyhedra define a corrugated layer of six-membered rings. The lay ers are connected along the unique b axis by interdigitated phenyl rings of the phenylphosphonate groups.