Cis- and trans-influences in [PtCl2(SPh2)(2)]

Authors
Johansson, MH Oskarsson, A Lovqvist, K Kiriakidou, F Kapoor, P
Citation
Mh. Johansson et al., Cis- and trans-influences in [PtCl2(SPh2)(2)], ACT CRYST C, 57, 2001, pp. 1053-1055
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
1053 - 1055
Database
ISI
SICI code
0108-2701(200109)57:<1053:CATI[>2.0.ZU;2-5
Abstract
Both cis- and trans-dichlorobis(diphenyl sulfide)platinum(II), [PtCl2(C12H1 0S)(2)], crystallize as mononuclear pseudo-square-planar complexes. In the cis compound, the Pt-Cl distances are 2.295 (2) and 2.319 (2) Angstrom, and the Pt-S distances are 2.280 (2) and 2.283 (2) Angstrom. In the trans comp ound, Pt is located on a centre of inversion and the Pt-Cl and Pt-S distanc es are 2.2786 (15) and 2.3002 (12) Angstrom, respectively.