Two isomorphous benzenesulfonamide crystal structures determined by intermolecular C-H center dot center dot center dot O,C-H center dot center dot center dot pi and C-H center dot center dot center dot Cl interactions

Authors
Bats, JW Frost, TM Hashmi, ASK
Citation
Jw. Bats et al., Two isomorphous benzenesulfonamide crystal structures determined by intermolecular C-H center dot center dot center dot O,C-H center dot center dot center dot pi and C-H center dot center dot center dot Cl interactions, ACT CRYST C, 57, 2001, pp. 1081-1083
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
1081 - 1083
Database
ISI
SICI code
0108-2701(200109)57:<1081:TIBCSD>2.0.ZU;2-2
Abstract
The title compounds, N-[5-(4-chlorophenyl)furan-2-ylmethyl]4-methyl-N-(prop -2-ynyl)benzenesulfonamide, (Ia), and N-[5(2-chlorophenyl)furan-2-ylmethyl] -4-methyl-N-(prop-2-ynyl)- benzenesulfonamide, (Ib), both C21H18ClNO3S, hav e isomorphous crystal structures. The crystal packing is mainly determined by intermolecular C-H . . .O and C-H . . . pi interactions. These interacti ons are very similar in (Ia) and (Ib). Additional intermolecular C-H . . . Cl interactions appear less important and are different in (Ia) and (Ib). T he different positions of the Cl atoms result in small variations of the cr ystal packing of the two compounds.