The near-room temperature current-voltage (I-V) characteristics of sma
ll structures made from the metal-cluster material Au-55[P(C6H5)(3)](1
2)Cl-6 were studied. It is shown that these electron-beam defined stru
ctures have highly nonlinear characteristics with features, including
a threshold voltage and scaling behavior, which are consistent with Co
ulomb charging of individual Au-55 cores in a disordered array. Applie
d radio frequency signals introduce plateaus in the I-V characteristic
s, which demonstrates the presence of coherent tunneling in these clus
ter systems. (C) 1997 American Institute of Physics.