The suppression effect of oxygen on Si incorporation in homoepitaxial
diamond films grown by microwave assisted chemical vapor deposition is
investigated by secondary ion mass spectrometry. The Si depth profile
in the multilayered diamond films continuously synthesized with diffe
rent oxygen addition shows that Si incorporation decreases with increa
sing oxygen addition into the plasma. A change in the interfacial comp
osition at the quartz glass due to oxygen-promoted surface chemistry m
ay be the origin of this suppression effect. (C) 1997 American Institu
te of Physics.