The operation of the intrinsic Stark effect at visible wavelengths is
reported, for both cubic and wurtzite type-II CdS-ZnSe strained layer
superlattices grown on CdS buffer layers on (111)A GaAs. An observed i
ncrease of the effective piezoelectric coefficient from the measured c
ubic bulk value is attributed to a nonlinear effect, as previously rep
orted for CdTe quantum wells [R. Andre, J. Cibert, Le Si Dang, J. Zema
n, and M. Zigone, Phys. Rev. B 53, 6951 (1996)]. Exciton peak shifts o
f 70 meV per decade change of excitation intensity are similar in magn
itude to those found in CdS-CdSe superlattices of similar period. Thes
e shifts are attributed to screening of the internal piezoelectric fie
lds by photoexcited carriers. Exciton peak shifts that are smaller by
an order of magnitude appear in CdS-ZnSe samples, grown on (100) ZnSe
buffers and therefore predicted to exhibit no piezoelectric effects of
any order. These small shifts, which we attribute to space charge bui
ldup, are a characteristic feature of type-II superlattices. (C) 1997
American Institute of Physics.