Sb. Zhang et A. Zunger, SURFACE-RECONSTRUCTION-ENHANCED SOLUBILITY OF N, P, AS, AND SB IN III-V SEMICONDUCTORS, Applied physics letters, 71(5), 1997, pp. 677-679
We show that surface reconstructions may play an essential role in det
ermining the equilibrium solubilities of N, P, As, and Sb in various m
-V compounds. In particular, anion-anion dimerization of the (001)-bet
a 2(2 X 4) surface can enhance the solubility of N near the surface in
GaAs, GaP, and InP by five, three, and two orders of magnitudes, resp
ectively, at 1000 K. With certain assumptions on the growth kinetics,
this high concentration of N may be frozen in as the crystal grows. (C
) 1997 American Institute of Physics.