A dramatic improvement of epoxide selectivity of [Ti,Al]-beta by ion-exchange with quaternary ammonium salts

Authors
Goa, Y Wu, P Tatsumi, T
Citation
Y. Goa et al., A dramatic improvement of epoxide selectivity of [Ti,Al]-beta by ion-exchange with quaternary ammonium salts, CHEM COMMUN, (18), 2001, pp. 1714-1715
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
18
Year of publication
2001
Pages
1714 - 1715
Database
ISI
SICI code
1359-7345(20010921):18<1714:ADIOES>2.0.ZU;2-Y
Abstract
Ion-exchange of [Ti,Al]-beta with quaternary ammonium acetates greatly enha nces the epoxide selectivity in the oxidation of alkenes with hydrogen pero xide; this is due to the selective poisoning of the acid sites without supp ressing the oxidation activity of Ti sites.