Control over directional metal-metal charge transfer in cyanide-bridged dimanganese complexes: effects of mu-CN linkage isomerism and ancillary ligand set

Authors
Anderson, KM Connelly, NG Llamas-Rey, E Orpen, AG Paul, RL
Citation
Km. Anderson et al., Control over directional metal-metal charge transfer in cyanide-bridged dimanganese complexes: effects of mu-CN linkage isomerism and ancillary ligand set, CHEM COMMUN, (18), 2001, pp. 1734-1735
Citations number
31
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
18
Year of publication
2001
Pages
1734 - 1735
Database
ISI
SICI code
1359-7345(20010921):18<1734:CODMCT>2.0.ZU;2-3
Abstract
Synthesis and characterisation of cyano-bridged complexes of the form [(eta -C5R4Me)L(ON)Mn(mu -XY)Mn(CO)(2)-L'(dppm)](Z) (X,Y = C,N; z = 1-3) shows t hat systematic variation of the orientation of the CN bridge and the nature and geometric arrangement of the ancillary ligands affords control of the direction and energy of metal-metal charge transfer in the mixed valence di cations.