One-step synthesis and redox properties of dodecahydro-3a,9a-diazaperylene- the most easily oxidized p-phenylenediamine

Authors
Rawashdeh, AMM Sotiriou-Leventis, C Gao, XR Leventis, N
Citation
Amm. Rawashdeh et al., One-step synthesis and redox properties of dodecahydro-3a,9a-diazaperylene- the most easily oxidized p-phenylenediamine, CHEM COMMUN, (18), 2001, pp. 1742-1743
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
18
Year of publication
2001
Pages
1742 - 1743
Database
ISI
SICI code
1359-7345(20010921):18<1742:OSARPO>2.0.ZU;2-5
Abstract
Dodecahydro-3a,9a-diazaperylene (DHDAP) was prepared in one step from p-phe nylenediamine and 1-bromo-3-chloropropane, and its first redox potential is 292 mV more negative than the first redox potential of N,N,N',N'-tetrameth yl-p-phenylenediamine (TMPD), thus becoming the most easily oxidized p-phen ylenediamine homologue.