Addition of diprotic nucleophiles to a C-60-tetrazine monoadduct: structural reassignment and correction of a novel rearrangement

Authors
Miller, GP Tetreau, MC Olmstead, MM Lord, PA Balch, AL
Citation
Gp. Miller et al., Addition of diprotic nucleophiles to a C-60-tetrazine monoadduct: structural reassignment and correction of a novel rearrangement, CHEM COMMUN, (18), 2001, pp. 1758-1759
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
18
Year of publication
2001
Pages
1758 - 1759
Database
ISI
SICI code
1359-7345(20010921):18<1758:AODNTA>2.0.ZU;2-W
Abstract
C-60-tetrazine Diels-Alder adducts bearing electron deficient dihydropyrida zine groups undergo chemoselective amination and hydration reactions upon a ddition of primary aliphatic amines and water, respectively, to form new ad ducts with 4,5-dihydropyrazole groups nested atop the [60]fullerene skeleto n.