Novel silver(I)-organic coordination polymers: conversion of extended structures in the solid state as driven by argentophilic interactions

Authors
Pan, L Woodlock, EB Wang, XT Lam, KC Rheingold, AL
Citation
L. Pan et al., Novel silver(I)-organic coordination polymers: conversion of extended structures in the solid state as driven by argentophilic interactions, CHEM COMMUN, (18), 2001, pp. 1762-1763
Citations number
26
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
18
Year of publication
2001
Pages
1762 - 1763
Database
ISI
SICI code
1359-7345(20010921):18<1762:NSCPCO>2.0.ZU;2-H
Abstract
Structurally distinct coordination polymers [Ag(bpp)]ClO4 1 and [Ag(bpp)]PF 6 2 [bpp = 1,3-bis(4-pyridyl)propane] have been assembled; the conversion o f 1 into 2 on treatment with NaPF6 is driven by argentophilic interactions and is the first such transformation reported for silver(I)-organic coordin ation polymers.