Addition of functional vinylzinc reagents to nitrones: synthesis of (E)-N-allylhydroxylamines and their rearrangement into (E)-O-allylhydroxylamines

Authors
Pandya, SU Garcon, C Chavant, PY Py, S Vallee, Y
Citation
Su. Pandya et al., Addition of functional vinylzinc reagents to nitrones: synthesis of (E)-N-allylhydroxylamines and their rearrangement into (E)-O-allylhydroxylamines, CHEM COMMUN, (18), 2001, pp. 1806-1807
Citations number
36
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
18
Year of publication
2001
Pages
1806 - 1807
Database
ISI
SICI code
1359-7345(20010921):18<1806:AOFVRT>2.0.ZU;2-4
Abstract
The vinylzinc reagents derived from hydrozirconation of alkynes and transme tallation add readily to nitrones to yield pure (E)-N-allylhydroxylamines; some of these rearrange into O-allylhydroxylamines.