P. Lettieri et al., A generalization of the Foscolo and Gibilaro particle-bed model to predictthe fluid bed stability of some fresh FCC catalysts at elevated temperatures, CHEM ENG SC, 56(18), 2001, pp. 5401-5412
The fluid-bed stability of three fresh FCC catalysts has been investigated
both experimentally and theoretically as a function of increasing temperatu
re. Values of the voidage at minimum bubbling conditions were obtained from
20 degreesC up to 650 degreesC, and compared with predictions given by the
Foscolo and Gibilaro particle bed model. The formulation of the drag force
proposed by Foscolo and Gibilaro has been generalized in order to correctl
y describe the homogeneous expansion of the three FCC catalysts. Consequent
ly, the procedure followed to obtain the Foscolo and Gibilaro stability cri
terion has been re-examined, and a generalized expression of their criterio
n is proposed. Predictions obtained from the generalized particle-bed model
were found in agreement with experimental data. This paper discusses also
the effect of the drag and buoyancy force in predicting correct trends for
epsilon (mb). To this end, results obtained using the Jean and Fan model ar
e reported. The physical origin of the stability of these catalysts is also
discussed, and the role of the hydrodynamic forces and interparticle force
s is examined. (C) 2001 Elsevier Science Ltd. All rights reserved.